
Overview
SF₆ is a colorless, odorless and highly stable gas. Its vapor density is five times that of air, making it exceptionally heavy and effective for specific uses. It remains in a vaporous state even at pressures of up to 250 PSI at normal operating temperatures. SF₆ is non-toxic, non-flammable, and has excellent electrical insulation and arc-quenching properties.
Applications
Electrical Industry:
Used as an insulating and arc-extinguishing medium in circuit breakers, transformers, and switchgear.
Medical Field:
Employed in certain medical procedures such as retinal surgeries.
Research and Development:
Used in tracer gas studies to detect gas leaks or measure gas diffusion.
Industrial Applications: Utilized for plasma etching in semiconductor manufacturing.
Special Effects Industry:
Used to create dense fog effects due to its high density.
SF6 Cylinder Sizes
- 5 liters: Max fill weight: 6.5 kg; Height with cap: 605 mm; Outer diameter: 140 mm; Tare with cap: 9 kg
- 10 liters: Max fill weight: 13.0 kg; Height with cap: 960 mm; Outer diameter: 140 mm; Tare with cap: 14 kg
- 20 liters: Max fill weight: 26.0 kg; Height with cap: 970 mm; Outer diameter: 204 mm; Tare with cap: 29 kg
- 40 liters: Max fill weight: 52.0 kg; Height with cap: 1,670 mm; Outer diameter: 204 mm; Tare with cap: 48 kg
- 43.5 liters: Max fill weight: 52.0 kg; Height with cap: 1,705 mm; Outer diameter: 204 mm; Tare with cap: 35 kg
- 600 liters (pressure drum): Max fill weight: 600 kg; Height: 2,120 mm; Outer diameter: 770 mm; Tare: 460 kg
Product Details
- Water Capacity (Litres):
- Available cylinder sizes: 5, 10, 20, 40, 43.5, and 600 liters.
- Working Pressure:
- Cylinders: 300 bar
- High-capacity pressure drum: 70 bar.
- Certification:
- Complies with IEC 60376
- Certifications include TPED (PI) for cylinders and drums
- Gas Capacity:
- Max fill weight per cylinder:
- 5 liters: 6.5 kg
- 10 liters: 13.0 kg
- 20 liters: 26.0 kg
- 40 liters: 52.0 kg
- 43.5 liters: 52.0 kg
- 600 liters: 600 kg.
- Max fill weight per cylinder:
- Cylinder Material:
Steel cylinders with a special gas-cylinder valve and protective caps.
6. Country of Origin:
- Cylinders and gas are manufactured in Germany and South Korea (plants in Bad Wimpfen and Onsan).
Safety Guidelines
General Safety
- Asphyxiation Risk:
- SF6 is non-toxic but displaces oxygen due to its high density, creating an asphyxiation risk in enclosed or poorly ventilated spaces, especially at lower levels.
- Ensure adequate ventilation in storage and working areas.
- Forced ventilation is necessary if SF6 is stored underground
- Ventilation:
- Natural and forced ventilation should be in place where SF6 is handled.
- Ventilation must be effective at ground levels to prevent the accumulation of the gas.
- Handling Precautions:
- Never allow SF6 containers to develop a vacuum as this could lead to contamination.
- Valves should always be securely closed immediately after use
Handling Contaminated SF6
- Decomposition Products:
- Electrical discharges can create toxic and corrosive decomposition products
- These may irritate the eyes, skin, and respiratory system.
- Warning signs include pungent odors and irritation within seconds.
- Personal Protective Equipment (PPE):
- When handling contaminated SF6, wear:
- Eye protection
- Body protection
- Respiratory protection
- Avoid inhaling or coming into contact with decomposition products.
- When handling contaminated SF6, wear:
- Safety Measures:
- Display operational instructions prominently.
- Conduct annual safety seminars on handling contaminated SF6.
Storage
- Conditions:
- Store SF6 in well-ventilated areas, away from direct sunlight, heat sources, and open flames.
- Ensure storage areas are secure to prevent cylinders from rolling or tipping.
- Precautions:
- No smoking, eating, or drinking is allowed during SF6 handling.
- Packaging should comply with safety standards and must not be exposed to excessive pressure Certification and Compliance
- SF6 must meet IEC 60376 standards to ensure its purity and safety for use.
- Contaminated SF6 should be analyzed and handled according to safety data sheets and regulations
Specifications
Purity:
- Minimum purity: 99.993%.
Impurities (Max Values):
- Air: 50 ppm wt
- CF4: 10 ppm wt
- Water: 0.65 ppm wt (Dew point: -65°C)
- Oil content: 1 ppm wt
- Acidity (as HF): 0.3 ppm wt.
Physical Properties:
- Critical Temperature: 45.58°C
- Critical Pressure: 37.59 bar
- Density:
- Gas: 6.07 g/L at 20°C and 1 bar
- Liquid: 1.56 kg/L at 0°C and 12.65 bar.
Cylinder and Packaging Specifications:
- Cylinder Capacities: 5 L, 10 L, 20 L, 40 L, 43.5 L, and 600 L
- Max Fill Weight (kg):
- 5 L: 6.5 kg
- 10 L: 13.0 kg
- 20 L: 26.0 kg
- 40 L: 52.0 kg
- 43.5 L: 52.0 kg
- 600 L: 600 kg
- Cylinder Pressure: 300 bar (70 bar for high-capacity drums).
Valve Connections:
- Connection Type: W 21.8 x 1/14” (DIN 477).
Compliance:
- Standards: IEC 60376, ASTM D2472-00, VDE 0373.
Toxicity:
- New SF6 is non-toxic and physiologically safe when handled correctly.
- Contaminated SF6 must be managed carefully due to the formation of toxic by-products during electrical discharges.
Thermal Properties:
- Sublimation Point: -63.9°C
- Melting Point: -50.8°C
- Heat of Sublimation: 153.2 kJ/kg
Additional Information
Packaging and Delivery:
- SF6 is shipped in steel cylinders of 5 L, 10 L, 20 L, 40 L, 43.5 L, and 600 L capacities.
- Tube trailers with up to 13 tons capacity are available for bulk transport.
- Cylinders are equipped with special gas-cylinder valves to ensure safety and prevent contamination.
Storage Recommendations:
- Cylinders should be stored upright, away from direct sunlight, heat, and open flames.
- Ventilation must be effective at ground level due to the gas’s high density.
SF6 ReUse Program:
- Solvay offers a recycling process for used SF6, ensuring environmental safety.
- Includes gas collection, analysis, and reintroduction into the production process.
Compliance and Quality:
- SF6 conforms to IEC 60376, ensuring minimum purity standards (99.993%).
- Manufactured in Germany and South Korea, meeting stringent safety and environmental standards.

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